3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
Safety Data Sheet Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document group: 19-5790-1 Version number: 2.00 Issue Date: 27/01/2015 Supersedes date: 26/01/2015 This Safety Data Sheet has been prepared in accordance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice (Safe Work Australia, December 2011) SECTION 1: Identification 1.1. Product identifier 3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
Product Identification Numbers 60-4402-9675-8
61-5001-0230-8 61-5001-9071-7
61-5001-1814-8 61-5002-9276-0
61-5001-2324-7 FN-5100-1135-9
61-5001-2714-9
61-5001-8715-0
1.2. Recommended use and restrictions on use Recommended use Abrasive Product For Industrial or Professional use only. 1.3. Supplier’s details Address:
3M Australia - Building A, 1 Rivett Road, North Ryde NSW 2113
Telephone: 136 136 E Mail:
productinfo.au@mmm.com
__________________________________________________________________________________________ Page: 1 of 10 www.3m.com.au 1.4. Emergency telephone number EMERGENCY: 1800 097 146 (Australia only) SECTION 2: Hazard identification This product is NOT classified as a hazardous chemical according to the Model Work Health and Safety Regulations, 2011. Refer to Section 14 of this Safety Data Sheets for product Dangerous Goods Classification. 2.1. Classification of the substance or mixture Not applicable. 2.2. Label elements Signal word Not applicable. Website:
3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
Symbols Not applicable. Pictograms Not applicable. 2.3. Other assigned/identified product hazards None known. 2.4. Other hazards which do not result in classification None known. SECTION 3: Composition/information on ingredients This material is a mixture.
Ingredient
CAS Nbr 409-21-2 32131-17-2 14808-60-7
% by Weight
Silicon Carbide Mineral
25 - 40 20 - 35 30 - 45 0 - 10 0.05 - 0.19
Nylon Fiber
Quartz
Cured resin
Mixture Mixture
Hookit™ Backing
__________________________________________________________________________________________ Page: 2 of 10 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Wash with soap and water. If signs/symptoms develop, get medical attention. Eye contact Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If swallowed No need for first aid is anticipated. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product.
3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
Hazardous Decomposition or By-Products Substance
Condition
Amine compounds. Carbon monoxide. Carbon dioxide. Hydrogen cyanide.
During combustion. During combustion. During combustion. During combustion. During combustion. During combustion.
Ammonia
Oxides of nitrogen.
5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Observe precautions from other sections. 6.2. Environmental precautions Not applicable. 6.3. Methods and material for containment and cleaning up Not applicable. SECTION 7: Handling and storage 7.1. Precautions for safe handling
__________________________________________________________________________________________ Page: 3 of 10 Avoid breathing of dust created by sanding, grinding or machining. Combustible dust may form by action of this product on another material (substrate). Dust generated from the substrate during use of this product may be explosive if in sufficient concentration with an ignition source. Dust deposits should not be allowed to accumulate on surfaces because of the potential for secondary explosions. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient CAS Nbr Agency Limit type Additional comments Quartz 14808-60-7 Australia OELs TWA(8 hours):0.1 mg/m3;Limit value not established: Quartz 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Nylon Fiber 32131-17-2 CMRG TWA(as respirable dust):5 mg/m3;TWA(as total dust):10 mg/m3 Silicon Carbide Mineral 409-21-2 Australia OELs TWA(Inspirable dust)(8 hours):10 mg/m3
3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association Australia OELs : Australia. Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment CMRG : Chemical Manufacturer's Recommended Guidelines
TWA: Time-Weighted-Average STEL: Short Term Exposure Limit
CEIL: Ceiling Sen: Sensitiser Sk: Absorption through the skin may be a significant source of exposure. 8.2. Exposure controls 8.2.1. Engineering controls Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment). 8.2.2. Personal protective equipment (PPE) Eye/face protection To minimise the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety glasses with side shields. Select and use eye protection in accordance with AS/NZS 1336. Eye protection should comply with the performance specifications of AS/NZS 1337. Skin/hand protection Wear appropriate gloves to minimise risk of injury to skin from contact with dust or physical abrasion from grinding or sanding. Respiratory protection Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates. For questions about suitability for a specific application, consult with your respirator manufacturer. Select and use respirators according to AS/NZS 1715. Respirators should comply with AS/NZS 1716 performance
specifications. For information about respirators, call 3M on 1800 024 464. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Solid. Appearance/Odour Solid abrasive product Odour threshold Not applicable. pH Not applicable.
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3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
Melting point/Freezing point Not applicable. Boiling point/Initial boiling point/Boiling range Not applicable. Flash point Not applicable. Evaporation rate Not applicable. Flammability (solid, gas) Not classified Flammable Limits(LEL) Not applicable. Flammable Limits(UEL) Not applicable. Vapour pressure Not applicable. Vapour density Not applicable. Relative density Not applicable. Water solubility Not applicable. Solubility- non-water Not applicable. Partition coefficient: n-octanol/water Not applicable. Autoignition temperature Not applicable. Decomposition temperature Not applicable. Viscosity Not applicable. SECTION 10: Stability and reactivity 10.1 Reactivity This material is considered to be non reactive under normal use conditions 10.2 Chemical stability Stable.
10.3. Conditions to avoid None known.
10.4. Possibility of hazardous reactions Hazardous polymerisation will not occur. 10.5 Incompatible materials None known. 10.6 Hazardous decomposition products Substance
Condition
None known. SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1 Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
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3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
__________________________________________________________________________________________ Page: 6 of 10 - This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material being abraded must also be considered. This product contains quartz silica. Quartz silica is a form of crystalline silica. Occupational exposure to inhaled crystalline silica has been associated with silicosis and lung cancer. No exposure to crystalline silica is expected during the normal handling and use of this product. Crystalline silica was not detected when air sampling was conducted during simulated use of similar products containing crystalline silica. Therefore, the health effects associated with crystalline silica are not expected during normal use of this product. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Silicon Carbide Mineral Dermal Rat LD50 > 2,000 mg/kg Silicon Carbide Mineral Ingestion Rat LD50 > 2,000 mg/kg Quartz Dermal LD50 estimated to be > 5,000 mg/kg Quartz Ingestion LD50 estimated to be > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Silicon Carbide Mineral Rat No significant irritation Quartz Professional judgement No significant irritation Serious Eye Damage/Irritation Name Species Value Silicon Carbide Mineral Professional judgement No significant irritation Skin Sensitisation For the component/components, either no data are currently available or the data are not sufficient for classification. Respiratory Sensitisation For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Quartz In Vitro Some positive data exist, but the data are not Dust created by grinding, sanding, or machining may cause irritation of the respiratory system. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin contact Mechanical skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching. Eye contact Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion No known health effects. Additional information:
3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
sufficient for classification
Quartz
In vivo
Some positive data exist, but the data are not sufficient for classification
Carcinogenicity Name
Route
Species
Value
Quartz
Inhalation
Human and animal
Carcinogenic.
Reproductive Toxicity Reproductive and/or Developmental Effects For the component/components, either no data are currently available or the data are not sufficient for classification. Target Organ(s) Specific Target Organ Toxicity - single exposure For the component/components, either no data are currently available or the data are not sufficient for classification.
Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value
Species
Test result
Exposure Duration occupational exposure
Quartz
Inhalation
silicosis
Causes damage to organs through prolonged or repeated exposure
Human
NOAEL Not available
Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Exposure Levels Refer Section 8.1 Control Parameters of this Safety Data Sheet. Interactive Effects Not determined. SECTION 12: Ecological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole. 12.1. Toxicity Acute aquatic hazard: Not acutely toxic to aquatic life by GHS criteria. Chronic aquatic hazard: Not chronically toxic to aquatic life by GHS criteria. No product test data available.
Material Nylon Fiber
CAS Number Organism Type
Exposure
Test endpoint Test result
32131-17-2
Data not available or
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3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
insufficient for classification Data not available or insufficient for classification Data not available or insufficient for classification
Silicon Carbide Mineral
409-21-2
Quartz
14808-60-7
12.2. Persistence and degradability Material
CAS Number Test type 32131-17-2 Data not available or
Duration
Study Type Test result
Protocol
Nylon Fiber
N/A
N/A
N/A
N/A
insufficient for classification Data not available or insufficient for classification
Silicon Carbide Mineral
409-21-2
N/A
N/A
N/A
N/A
Quartz
14808-60-7 Data not available or
N/A
N/A
N/A
N/A
insufficient for classification
12.3 : Bioaccumulative potential Material
CAS Number Test type 32131-17-2 Data not available or
Duration
Study Type Test result
Protocol
Nylon Fiber
N/A
N/A
N/A
N/A
insufficient for classification Data not available or insufficient for classification
Silicon Carbide Mineral
409-21-2
N/A
N/A
N/A
N/A
Quartz
14808-60-7 Data not available or
N/A
N/A
N/A
N/A
insufficient for classification
12.4. Mobility in soil Please contact manufacturer for more details
12.5 Other adverse effects No information available. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations.
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3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. If no other disposal options are available, waste product may be placed in a landfill properly designed for industrial waste. SECTION 14: Transport Information Australian Dangerous Goods Code (ADG) - Road/Rail Transport UN No.: Not applicable. Proper shipping name: Not applicable. Class/Division: Not applicable. Sub Risk: Not applicable.
Packing Group: Not applicable. Hazchem Code: Not applicable IERG: Not applicable. International Air Transport Association (IATA) - Air Transport UN No.: Not applicable. Proper shipping name: Not applicable. Class/Division: Not applicable. Sub Risk: Not applicable. Packing Group: Not applicable. International Maritime Dangerous Goods Code (IMDG)- Marine Transport UN No.: Not applicable. Proper shipping name: Not applicable. Class/Division: Not applicable. Sub Risk: Not applicable.
Packing Group: Not applicable. Marine Pollutant: Not applicable.
__________________________________________________________________________________________ Page: 9 of 10 DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Safety Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Australian Inventory Status: This product is definded as an article under the Industrial Chemicals (Notification and Assessment) Act 1989, as amended, and is exempt from inventory requirements under the Industrial Chemicals (Notification and Assessment) Act 1989 as amended. Poison Schedule: This product is an article therefore the Standard for the Uniform Scheduling of Medicines and Poisons Schedule is not applicable. SECTION 16: Other information Revision information: Conversion to GHS format SDS.
3M™ Scotch-Brite™ Products, 7448, 7448B, 7468
Greenguard ® is a United States based program. The ‘Low VOC’ reference related to United States Federal and State regulations exemptions for some solvents. 3M Australia SDSs are available at www.3m.com.au
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